A new member of the fusaricidin family – structure elucidation and synthesis of fusaricidin E
نویسندگان
چکیده
Two hitherto unknown fusaricidins were obtained from fermentation broths of three Paenibacillus strains. After structure elucidation based on tandem mass spectrometry and NMR spectroscopy, fusaricidin E was synthesized to confirm the structure and the suggested stereochemistry. The synthesis was based on a new strategy which includes an efficient access to the 15-guanidino-3-hydroxypentadecanoyl (GHPD) side chain from erucamide.
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عنوان ژورنال:
دوره 13 شماره
صفحات -
تاریخ انتشار 2017